Cocaine and Metabolites on Luna HILIC 3u 100x2.0

Cocaine and Metabolites on Luna HILIC 3u 100x2.0
LC Conditions
Column

Luna 3 µm HILIC 200 Å, LC Column 100 x 2 mm, Ea

Brand

Luna

Part No

00D-4449-B0

Phase Name

HILIC

Elution Type

Gradient

Mobile Phase

A: 95/5 ACN/100mM NH4 Formate pH 3.2

B: 50/45/5 ACN/H2O/100mM NH4 Formate pH 3.2

Gradient Profile

Step No.

Time(min)

%A

%B

1

0

100

0

2

1.7

100

0

3

4.8

45

55

4

6.5

45

55

5

6.6

100

0

6

12.6

100

0

Flow Rate

0.40 mL/min

Temperature

22°C

Detection

Mass Spectrometer (MS) @ (22°C)

Detection Info
Sample Notes

SecurityGuard™ Guard Cartridge System extends column lifetime. - SecurityGuard Cartridges, HILIC 4 x 2.0mm, 10/Pk Part No.: AJ0-8328 - Holder Part No.: KJ0-4282

Order Items Used in This Application

Luna 3 µm HILIC 200 Å, LC Column 100 x 2 mm, Ea
00D-4449-B0

Luna 3 µm HILIC 200 Å, LC Column 100 x 2 mm, Ea

View Product

  • 1. Cocaine
  • 2. Norcocaine
  • 3. Ecgonine methyl ester
  • 4. Benzoylecgonine
  • 5. Ecgonine
-OEChem-06211003152D<br><br> 43 45  0     1  0  0  0  0  0999 V2000<br>    5.4641   -0.9895    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0<br>    8.4026   -2.1834    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0<br>    6.7084   -2.5435    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0<br>    4.5981    0.5105    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0<br>    8.3010    2.2955    0.0000 N   0  0  3  0  0  0  0  0  0  0  0  0<br>    8.7788    0.3469    0.0000 C   0  0  3  0  0  0  0  0  0  0  0  0<br>    9.0376    1.3129    0.0000 C   0  0  3  0  0  0  0  0  0  0  0  0<br>    7.2437   -0.8962    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0<br>   10.6108   -0.4119    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0<br>   10.8696    0.5541    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0<br>    6.4347    0.5051    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0<br>    6.3301   -0.4895    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0<br>    7.8010    3.1615    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0<br>    7.4516   -1.8744    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0<br>    4.5981   -0.4895    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0<br>    8.6106   -3.1615    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0<br>    3.7320   -0.9895    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0<br>    3.7320   -1.9895    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0<br>    2.8660   -0.4895    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0<br>    2.8660   -2.4895    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0<br>    2.0000   -0.9895    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0<br>    2.0000   -1.9895    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0<br>    8.9008   -0.4943    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0<br>    8.9986    0.4638    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0<br>    6.7618   -1.2864    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0<br>   10.3987   -0.9945    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0<br>   11.2021   -0.5983    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0<br>   11.4609    0.3676    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0<br>   11.0817    1.1367    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0<br>    6.3324    1.1166    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0<br>    5.8149    0.4862    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0<br>    5.8102   -0.1518    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0<br>    8.3380    3.4715    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0<br>    7.4910    3.6984    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0<br>    7.2641    2.8515    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0<br>    8.0041   -3.2904    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0<br>    8.7395   -3.7680    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0<br>    9.2170   -3.0326    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0<br>    4.2690   -2.2995    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0<br>    2.8660    0.1305    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0<br>    2.8660   -3.1095    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0<br>    1.4631   -0.6795    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0<br>    1.4631   -2.2995    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0<br> 12  1  1  1  0  0  0<br>  1 15  1  0  0  0  0<br>  2 14  1  0  0  0  0<br>  2 16  1  0  0  0  0<br>  3 14  2  0  0  0  0<br>  4 15  2  0  0  0  0<br>  5  6  1  0  0  0  0<br>  5  7  1  0  0  0  0<br>  5 13  1  0  0  0  0<br>  6  8  1  0  0  0  0<br>  6  9  1  0  0  0  0<br>  6 23  1  0  0  0  0<br>  7 10  1  0  0  0  0<br>  7 11  1  0  0  0  0<br>  7 24  1  0  0  0  0<br>  8 12  1  0  0  0  0<br>  8 14  1  1  0  0  0<br>  8 25  1  0  0  0  0<br>  9 10  1  0  0  0  0<br>  9 26  1  0  0  0  0<br>  9 27  1  0  0  0  0<br> 10 28  1  0  0  0  0<br> 10 29  1  0  0  0  0<br> 11 12  1  0  0  0  0<br> 11 30  1  0  0  0  0<br> 11 31  1  0  0  0  0<br> 12 32  1  0  0  0  0<br> 13 33  1  0  0  0  0<br> 13 34  1  0  0  0  0<br> 13 35  1  0  0  0  0<br> 15 17  1  0  0  0  0<br> 16 36  1  0  0  0  0<br> 16 37  1  0  0  0  0<br> 16 38  1  0  0  0  0<br> 17 18  2  0  0  0  0<br> 17 19  1  0  0  0  0<br> 18 20  1  0  0  0  0<br> 18 39  1  0  0  0  0<br> 19 21  2  0  0  0  0<br> 19 40  1  0  0  0  0<br> 20 22  2  0  0  0  0<br> 20 41  1  0  0  0  0<br> 21 22  1  0  0  0  0<br> 21 42  1  0  0  0  0<br> 22 43  1  0  0  0  0<br>M  END
Compound Name

Cocaine

CID

5760

Molecular Formula

C17H21NO4

Molecular Weight

303

No. Hydrogen Bond Acceptors

5

Similar Applications

Improved Performance

ZB-5MSplus Drugs of Abuse

Zebron ZB-5MSplus, GC Cap. Column 30 m x 0.25 mm x 0.25 µm, EA

23258

Application Specific

Cocaine and opiates by GCMS on a ZB-Drug-1

Zebron ZB-Drug-1, GC Cap. Column 10 m x 0.18 mm x 0.18 µm, Ea

20811

Standard

Cocaine and opiates by GCMS on a ZB-5MS

Zebron ZB-5MS, GC Cap. Column 20 m x 0.18 mm x 0.18 µm, Ea

20809

Reversed Phase

Narcotics 8-mix at Neutral pH on Kinetex 2.6 µm C18, 50 x 2.1mm

Kinetex 2.6 µm C18 100 Å, LC Column 50 x 2.1 mm, Ea

19184

Reversed Phase

Extraction of Cocaine-NIDA5 Using strata X-C on Kinetex 2.6µm C18 50 x 2.1mm ID by LCMS

Kinetex 2.6 µm C18 100 Å, LC Column 50 x 2.1 mm, Ea

18843

Application Specific

Drug screen by MSD on a ZB-Drug1

Zebron ZB-Drug-1, GC Cap. Column 10 m x 0.18 mm x 0.18 µm, Ea

18175

Hydrophilic Interaction

Cocaine and Metabolites on Luna HILIC 3u 100x2.0

Luna 3 µm HILIC 200 Å, LC Column 100 x 2 mm, Ea

17914

Standard

Drug Screen on ZB-XLB

Zebron ZB-XLB, GC Cap. Column 30 m x 0.25 mm x 0.50 µm, Ea

16463

Drug screen on ZB-5MSi

16421

High Temperature

Drug Screen on ZB-1HT

Zebron ZB-1HT, GC Cap. Column 30 m x 0.25 mm x 0.10 µm, Ea

16227

Standard

Common Drug Screen on ZB-50

Zebron ZB-50, GC Cap. Column 30 m x 0.25 mm x 0.25 µm, Ea

16012

Standard

Common Drug Screen on ZB-35

Zebron ZB-35, GC Cap. Column 30 m x 0.25 mm x 0.25 µm, Ea

16010

Standard

Common Drug Screen on ZB-5MS

Zebron ZB-5MS, GC Cap. Column 20 m x 0.18 mm x 0.18 µm, Ea

16009

Common Drug Screen on ZB-1MS

16008

Drug Screen on Zebron ZB-1MS 12m x 0.20mm x 0.33um

15869

Standard

Drug Screen on Zebron ZB-5MS 20m x 0.18mm x 0.18um

Zebron ZB-5MS, GC Cap. Column 20 m x 0.18 mm x 0.18 µm, Ea

15868

Drug Screen on Zebron ZB-1MS 20m x 0.18mm x 0.18um

15867

Cocaine (BSTFA Derivatization) on ZB1ms 20x0.18x0.18

15573

Standard

Cocaine on ZB5ms 20x0.18x0.18

Zebron ZB-5MS, GC Cap. Column 20 m x 0.18 mm x 0.18 µm, Ea

15568

Standard

Cocaine and Barbiturates on ZB-5

Zebron ZB-5, GC Cap. Column 30 m x 0.25 mm x 0.25 µm, Ea

14904

Standard

Cocaine on ZB-5

Zebron ZB-5, GC Cap. Column 15 m x 0.25 mm x 0.25 µm, Ea

14785

Standard

Drugs of Abuse

Zebron ZB-1, GC Cap. Column 15 m x 0.25 mm x 0.25 µm, Ea

6567

Standard

Drugs of Abuse

Zebron ZB-1, GC Cap. Column 15 m x 0.53 mm x 0.50 µm, Ea

1080